Premium
Nanoparticle Synthesis in Engineered Organic Nanoscale Reactors
Author(s) -
Shchukin D. G.,
Sukhorukov G. B.
Publication year - 2004
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/adma.200306466
Subject(s) - microreactor , materials science , nanotechnology , polyelectrolyte , nanomaterials , nanoparticle , amorphous solid , nanoscopic scale , nanoreactor , chemical engineering , polymer , catalysis , composite material , organic chemistry , chemistry , engineering
In this review, the recent achievements in the synthesis of inorganic nanomaterials inside the spatially confined volume of individual micro‐ and submicroreactors (emulsions, micelles, organized thin films, polyelectrolyte capsules, etc.) are presented. The advantages and shortcomings of each type of microreactor are discussed. Particular attention is paid to polyelectrolyte capsules as confined microreactors with controlled shell permeability and the possibility of shell engineering on the nanolevel, thus tailoring different functionalities. Nanomaterials synthesized inside a confined multifunctional microreactor have several advantages: i) absence of particle aggregates, ii) amorphous or metastable crystal phases, and iii) unique composite inorganic/inorganic and inorganic/organic structures.