Blue Luminescence of Facial Tris(quinolin‐8‐olato)aluminum( III ) in Solution, Crystals, and Thin Films | Zendy

Muccini M. | Zendy; Loi M. A. | Zendy; Kenevey K. | Zendy; Zamboni R. | Zendy; Masciocchi N. | Zendy; Sironi A. | Zendy

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Blue Luminescence of Facial Tris(quinolin‐8‐olato)aluminum( III ) in Solution, Crystals, and Thin Films

Author(s) -

Muccini M.,

Loi M. A.,

Kenevey K.,

Zamboni R.,

Masciocchi N.,

Sironi A.

Publication year - 2004

Publication title -

advanced materials

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 10.707

H-Index - 527

eISSN - 1521-4095

pISSN - 0935-9648

DOI - 10.1002/adma.200305421

Subject(s) - materials science , tris , luminescence , solid state , aluminium , oled , solid solution , thin film , chemical engineering , photochemistry , chemistry , optoelectronics , nanotechnology , metallurgy , biochemistry , layer (electronics) , engineering

Isolation, mass production, and characterization in solution and in the solid state of the facial stereoisomer of tris(quinolin‐8‐olato)aluminum( III ) (Alq 3 ) is reported. A phase‐ transformation diagram shows how to selectively produce the two blue‐emitting polymorphs of the fac isomer (γ‐ and δ‐Alq 3 ; see Figure) via a solid‐to‐solid reaction, opening the route to the development of blue‐light‐emitting Alq 3 ‐based OLEDs.

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