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Electrochemistry of Poly(3,4‐alkylenedioxythiophene) Derivatives
Author(s) -
Groenendaal L.,
Zotti G.,
Aubert P.H.,
Waybright S.M.,
Reynolds J.R.
Publication year - 2003
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/adma.200300376
Subject(s) - electrochromism , materials science , electrochemistry , electrochromic devices , conductive polymer , nanotechnology , polymer , doping , characterization (materials science) , polymer science , optoelectronics , electrode , chemistry , composite material
An overview of the electrochemistry of poly(3,4‐alkylenedioxythiophene)s (PXDOTs) is presented. As a class of conducting and electroactive polymers that can exhibit high and quite stable conductivities, a high degree of optical transparency as a conductor, and the ability to be rapidly switched between conducting doped and insulating neutral states, PXDOTs have attracted attention across academia and industry. Numerous fundamental aspects are addressed here in detail, ranging from the electrochemical synthesis of PXDOTs, a variety of in‐situ characterization techniques, the broad array of properties accessible, and morphological aspects. Finally, two electrochemically‐driven applications, specifically electrochromism and chemical sensors of PXDOTs are discussed.