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Organoporous hosts with adjustable molecular environments
Author(s) -
Swift Jennifer A.,
Russell Victoria A.,
Ward Michael D.
Publication year - 1997
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/adma.19970091513
Subject(s) - nanoporous , materials science , nanotechnology , motif (music) , crystallography , chemistry , physics , acoustics
Tailored organoporous materials —the organic counterparts to inorganic nanoporous materials–have been prepared by a design strategy based on the observation that guanidinium organosulfonates (C(NH 2 ) 3 ⊕ RSO 3 ⊖ ) crystallize predictably in layered structures. The extension to disulfonates is shown to produce, among others, the motif shown in the Figure (the ovals are organodisulfonate pillars and the rectangles, guests).