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Novel κ‐type organic metal based on a bis‐fused tetrathiafulvalene derivative
Author(s) -
Misaki Yohji,
Miura Takeshi,
Taniguchi Masateru,
Fujiwara Hideki,
Yamabe Tokio,
Mori Takehiko,
Mori Hatsumi,
Tanaka Shoji
Publication year - 1997
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/adma.19970090906
Subject(s) - tetrathiafulvalene , materials science , substituent , metal , derivative (finance) , superconductivity , metal organic framework , organic superconductor , electrical resistivity and conductivity , type (biology) , inorganic chemistry , organic chemistry , molecule , chemistry , condensed matter physics , metallurgy , ecology , physics , engineering , adsorption , economics , financial economics , electrical engineering , biology
A novel k‐type organic metal based on 4,5,‐cyclohexeno‐TTP (where TTP is bis‐fused tetrathiafulvalene, TTF), see Figure, is reported. The synthesis, structure, and electrical properties are described. It is suggested that, following this demonstration of a TTF‐based organic metal without a chalcogeno‐based substituent, further CH‐TTP salts should be investigated for conductivity and superconductivity.