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Formation of non‐stoichiometric salts of tetrathiafulvalene in an acidic medium
Author(s) -
Farnia Giuseppe,
Sandonà Giancarlo,
Marcuzzi Franco
Publication year - 1996
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/adma.19960080908
Subject(s) - stoichiometry , tetrathiafulvalene , materials science , valence (chemistry) , inorganic chemistry , base (topology) , chloride , organic chemistry , molecule , chemistry , metallurgy , mathematical analysis , mathematics
A new, convenient synthetic pathway to non‐stoichiometric mixed‐valence tetrathiafulvalenium salts is presented. Study of TTF · squarilium chloride salts produced using this method provides further evidence that the generation of the radical species takes place through acid‐base reactions.