Nanocrystal gold molecules | Zendy

Whetten Robert L. | Zendy; Khoury Joseph T. | Zendy; Alvarez Marcos M. | Zendy; Murthy Srihari | Zendy; Vezmar Igor | Zendy; Wang Z. L. | Zendy; Stephens Peter W. | Zendy; Cleveland Charles L. | Zendy; Luedtke W. D. | Zendy; Landman Uzi | Zendy

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Nanocrystal gold molecules

Author(s) -

Whetten Robert L.,

Khoury Joseph T.,

Alvarez Marcos M.,

Murthy Srihari,

Vezmar Igor,

Wang Z. L.,

Stephens Peter W.,

Cleveland Charles L.,

Luedtke W. D.,

Landman Uzi

Publication year - 1996

Publication title -

advanced materials

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 10.707

H-Index - 527

eISSN - 1521-4095

pISSN - 0935-9648

DOI - 10.1002/adma.19960080513

Subject(s) - nanocrystal , materials science , monolayer , molecule , nanotechnology , octahedron , colloidal gold , self assembly , crystallography , crystal structure , nanoparticle , organic chemistry , chemistry

Gold nanocrystals passivated by self‐assembled monolayers of straightchain alkylhiolate molecules have been obtained as highly purified molecular materials of high intrinsic stability. Evidence is presented for a predicted discrete sequence of energetically optimal fcc structures of a truncated octahedral morphological motif (see cover). The nanocrystal materials have a propensity to form extended superlattics, such as that in the Figure.

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