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Layered and pillared metal( IV ) phosphates and phosphonates
Author(s) -
Alberti Giulio,
Casciola Mario,
Costantino Umberto,
Vivani Riccardo
Publication year - 1996
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/adma.19960080405
Subject(s) - zirconium , materials science , zirconium phosphate , metal , inorganic chemistry , catalysis , proton , phosphate , organic chemistry , chemistry , metallurgy , physics , quantum mechanics
Proton conductors, catalysts, and solar energy storage materials are some of the potential uses of various crystalline acid salts of tetravalent metals. Results obtained on a large number of metal( IV ) phosphates and phosphonates are reviewed, the α‐ and β‐structured layered metal( IV ) phosphates and the organic derivatives of zirconium phosphates being emphasized. Methods of preparation and the structures determined—especially layered and pillared—are described.