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Phenyl groups as molecular fasteners: Phenyltelluro‐substituted tetrathiafulvalenes
Author(s) -
Khodorkovsky Vladimir Y.,
Wang Changsheng,
Becker James Y.,
Ellern Arkady,
Shapiro Lev,
Bernstein Joel
Publication year - 1994
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/adma.19940060907
Subject(s) - tetrathiafulvalene , stacking , materials science , molecule , molecular wire , component (thermodynamics) , crystallography , organic chemistry , thermodynamics , chemistry , physics
Phenyltelluro–tetrathiafulvalene (TTF) derivatives , for example those shown in the Figure, are reported to exhibit one‐component two‐dimensional networks of shortened molecular interactions and electrical conductivities that are unsually high for neutral organic molecules. Evidence for stacking of TTF groups—despite the bulky phenyl groups—is presented.