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Magnetic properties of ferrocene‐based conjugated polymers
Author(s) -
Hmyene Mohamed,
Yassar Abderrahim,
Escorne Marcel,
PercheronGuegan Annick,
Garnier Francis
Publication year - 1994
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/adma.19940060707
Subject(s) - conjugated system , materials science , polymer , ferrocene , ferromagnetism , nanotechnology , spin (aerodynamics) , bridge (graph theory) , chemical physics , polymer science , condensed matter physics , chemistry , electrochemistry , composite material , physics , medicine , electrode , thermodynamics
A novel route to organic ferromagnetic materials is proposed that is based on the stability of spin‐containing organometallic moieties such as ferricenium and the electronic or topological interactions contributed by a polymer. The magnetic properties of the new high‐spin polymers (see Figure) are shown to be sensitively dependent on the chemical nature of the bridge linking the ferricenium units.