Germanium nanoclusters: Chemical vapor deposition of digermane in zeolite Y and mordenite | Zendy

Dag ÖMer | Zendy; Kuperman Alex | Zendy; Ozin Geoffrey A. | Zendy

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Germanium nanoclusters: Chemical vapor deposition of digermane in zeolite Y and mordenite

Author(s) -

Dag ÖMer,

Kuperman Alex,

Ozin Geoffrey A.

Publication year - 1994

Publication title -

advanced materials

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 10.707

H-Index - 527

eISSN - 1521-4095

pISSN - 0935-9648

DOI - 10.1002/adma.19940060211

Subject(s) - nanoclusters , mordenite , chemical vapor deposition , zeolite , germanium , materials science , deposition (geology) , chemical engineering , molecular sieve , diamond , nanotechnology , inorganic chemistry , silicon , organic chemistry , adsorption , composite material , chemistry , metallurgy , catalysis , engineering , paleontology , sediment , biology

Uniform arrays of intrazeolite germanium nanoclusters have been produced by the topotactic chemical vapor deposition of digermane within the diamond network of α‐cages of acid zeolite Y and the main channel of mordenite. The conditions within the zeolite hosts enusure that the Ge 2 H 6 CVD‐type anchored precursors self‐assemble to produce the anchored (Ge 8 ) n ⊕ nanoclusters shown in the Figure.

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