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Ring‐opening polymerization of metallocenophanes
Author(s) -
Manners Ian
Publication year - 1994
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/adma.19940060115
Subject(s) - materials science , ferrocene , polymerization , polymer , ring (chemistry) , yield (engineering) , ring opening polymerization , polymer chemistry , nanotechnology , composite material , organic chemistry , electrode , chemistry , electrochemistry
The development of processable high molecular weight polymers with skeletal transition metal atoms represents a synthetic challenge that, if overcome, can be expected to yield a variety of materials with novel electrical, optical, magnetic, or preceramic properties. Recent work has shown that the ringopening polymerization (ROP) of strained, ring‐tilted [11]‐ or [2] metallocenophanes provides a route to a variety of welldefined, ferrocene‐backbone polymers with molecular weights of over 1 in several cases.
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