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The synthesis and magnetic behavior of the first mesogenic μ‐oxo‐bridged iron( III ) complex
Author(s) -
Galyametdinov Yury,
Ivanova Galina,
Griesar Klaus,
Prosvirin Andrew,
Ovchinnikov Igor,
Haase Wolfgang
Publication year - 1992
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/adma.19920041106
Subject(s) - mesogen , mesophase , liquid crystal , materials science , schiff base , crystallography , ferromagnetism , ion , liquid crystalline , polymer chemistry , organic chemistry , condensed matter physics , chemistry , optoelectronics , physics
Metallomesogens are under investigation as potential molecular ferromagnets, ferroelectrics, and second order nonlinear optical materials. Metallomesogens containing Fe III ions are rare but here, the first liquid crystal containing two Fe III ions and teh first complex of Fe III exhibiting a nematic mesophase is reported. The synthesis and magnetic behavior of the μ‐oxo‐bridged complex of Fe III and Schiff's base are discussed.