meso ‐(Tetraphenylporphinato)manganese( III )‐tetracyanoethenide, [Mn III TPP] ::⊕ [TCNE] .⊖ . A New Structure‐Type Linear‐Chain Magnet with a T c  of 18K | Zendy

Miller Joel S. | Zendy; Calabrese Joseph C. | Zendy; McLean R. Scott | Zendy; Epstein Arthur J. | Zendy

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meso ‐(Tetraphenylporphinato)manganese( III )‐tetracyanoethenide, [Mn III TPP] ::⊕ [TCNE] .⊖ . A New Structure‐Type Linear‐Chain Magnet with a T c of 18K

Author(s) -

Miller Joel S.,

Calabrese Joseph C.,

McLean R. Scott,

Epstein Arthur J.

Publication year - 1992

Publication title -

advanced materials

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 10.707

H-Index - 527

eISSN - 1521-4095

pISSN - 0935-9648

DOI - 10.1002/adma.19920040710

Subject(s) - manganese , materials science , magnet , molecular magnets , crystallography , type (biology) , chain (unit) , physics , magnetization , chemistry , magnetic field , metallurgy , ecology , astronomy , biology , quantum mechanics

Cooperative magnetic interactions in molecular materials at room temperature are the goal of much interdisciplinary research. The title compound is shown to have a T c of 18 K and to be of a new structural type which makes it a suitable model for the previously reported, disordered, infusible V(TCNE), which is a room‐temperature magnet. The synthesis and structure of the new material are discussed.

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