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The first example of a tridentate azamacrocyclic metallomesogen
Author(s) -
Lattermann Günter,
Schmidt Steven,
Kleppinger Ralf,
Wendorff Joachim Heinz
Publication year - 1992
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/adma.19920040105
Subject(s) - mesogen , materials science , amine gas treating , molecule , metal , crystallography , liquid crystal , liquid crystalline , organic chemistry , chemistry , metallurgy , optoelectronics
The introduction of a metal into a mesogenic molecule can result in a complex with interesting electrical and magnetic properties. By reacting the non‐mesogenic cyclic amine shown in the figure with Ni(NO 3 ) 2 · 6H 2 O in absolute THF the first member of a new class of columnar liquid‐crystalline metal complexes with three nitrogen atoms as donor groups has been prepared.