A conducting thallium salt of 2,5‐dimethyl‐ N, N ′‐dicyanoquinone‐diimine, [2,5‐DMe‐DCNQI] 2 Tl: Comparison with other related radical anion salts | Zendy

Hünig Siegfried | Zendy; Meixner Hubert | Zendy; Metzenthin Tobias | Zendy; Langohr Uwe | Zendy; von Schütz Jost Ulrich | Zendy; Wolf HansChristopf | Zendy; Tillmanns Ekkehart | Zendy

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A conducting thallium salt of 2,5‐dimethyl‐ N, N ′‐dicyanoquinone‐diimine, [2,5‐DMe‐DCNQI] 2 Tl: Comparison with other related radical anion salts

Author(s) -

Hünig Siegfried,

Meixner Hubert,

Metzenthin Tobias,

Langohr Uwe,

von Schütz Jost Ulrich,

Wolf HansChristopf,

Tillmanns Ekkehart

Publication year - 1990

Publication title -

advanced materials

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 10.707

H-Index - 527

eISSN - 1521-4095

pISSN - 0935-9648

DOI - 10.1002/adma.19900020805

Subject(s) - thallium , salt (chemistry) , knight shift , ion , diimine , copper , materials science , ligand (biochemistry) , atom (system on chip) , inorganic chemistry , crystallography , chemistry , organic chemistry , physics , biochemistry , superconductivity , receptor , computer science , metallurgy , embedded system , catalysis , quantum mechanics

A radical anion salt based on thallium (see figure, where M = Tl) has been prepared. It is found to be the only such conducting compound, except the copper analogue, which shows a positive NMR knight shift indicating an electronic interaction between the central atom and the ligand.

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