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Solid State NMR spectroscopy in polymer science
Author(s) -
Blümich Bernhard,
Hagemeyer Alfred,
Schaefer Dieter,
SchmidtRohr Klaus,
Spiess Hans W.
Publication year - 1990
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/adma.19900020203
Subject(s) - materials science , polymer , solid state nuclear magnetic resonance , amorphous solid , nuclear magnetic resonance spectroscopy , molecule , spectroscopy , chemical physics , nuclear magnetic resonance crystallography , spin diffusion , diffusion , nuclear magnetic resonance , crystallography , fluorine 19 nmr , organic chemistry , chemistry , thermodynamics , physics , quantum mechanics , composite material
The properties of solid polymers are determined to a large extent by the structure, order, and dynamics of the molecules which make up the polymers on a molecular scale as well as by the morphological domain structure involving the size and type of crystalline, amorphous and interfacial phases. Solid state NMR spectroscopy is a method particularly suited to the investigation of the properties of individual molecules since their resonance frequency depends on the structure and on the orientation of a molecular segment in the magnetic field. In addition, morphological aspects can be studied by following the spin diffusion between individual phases. This review covers NMR techniques devised recently to address such polymer specific questions.