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Asymmetric Supercapacitors Based on Graphene/MnO 2 Nanospheres and Graphene/MoO 3 Nanosheets with High Energy Density
Author(s) -
Chang Jian,
Jin Meihua,
Yao Fei,
Kim Tae Hyung,
Le Viet Thong,
Yue Hongyan,
Gunes Fethullah,
Li Bing,
Ghosh Arunabha,
Xie Sishen,
Lee Young Hee
Publication year - 2013
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm201301851
Subject(s) - materials science , supercapacitor , graphene , electrolyte , capacitance , oxide , power density , electrode , composite number , chemical engineering , nanotechnology , composite material , power (physics) , metallurgy , chemistry , physics , quantum mechanics , engineering
Asymmetric supercapacitors with high energy density are fabricated using a self‐assembled reduced graphene oxide (RGO)/MnO 2 (GrMnO 2 ) composite as a positive electrode and a RGO/MoO 3 (GrMoO 3 ) composite as a negative electrode in safe aqueous Na 2 SO 4 electrolyte. The operation voltage is maximized by choosing two metal oxides with the largest work function difference. Because of the synergistic effects of highly conductive graphene and highly pseudocapacitive metal oxides, the hybrid nanostructure electrodes exhibit better charge transport and cycling stability. The operation voltage is expanded to 2.0 V in spite of the use of aqueous electrolyte, revealing a high energy density of 42.6 Wh kg −1 at a power density of 276 W kg −1 and a maximum specific capacitance of 307 F g −1 , consequently giving rise to an excellent Ragone plot. In addition, the GrMnO 2 //GrMoO 3 supercapacitor exhibits improved capacitance with cycling up to 1000 cycles, which is explained by the development of micropore structures during the repetition of ion transfer. This strategy for the choice of metal oxides provides a promising route for next‐generation supercapacitors with high energy and high power densities.