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Selective Wavelength Enhanced Photochemical and Photothermal H 2 Generation of Classical Oxide Supported Metal Catalyst
Author(s) -
Ng Serene Wen Ling,
Gao Minmin,
Lu Wanheng,
Hong Minghui,
Ho Ghim Wei
Publication year - 2021
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.202104750
Subject(s) - photothermal therapy , catalysis , materials science , photochemistry , photothermal effect , oxide , nanotechnology , chemistry , organic chemistry , metallurgy
Conventional views of constructing simply broadband catalysts for photothermal‐enhanced catalysis do not realize that without designating photochemical and photothermal conversion to their optimal working spectra can lead to a performance trade‐off. Here, spectrally selective designed photoredox and photothermal heating functions of a classical oxide supported metal catalyst are demonstrated, which exhibits markedly improved hydrogen reactivity. While photothermal hydrogen producing catalysis is previously demonstrated, distinctive wavelength dominant redox and thermal phenomena are not studied due to the complex interdependent behavior they exhibit. The exceptionally high H 2 evolution rate of 30.2 mmol g −1 h −1 (≈74 times that of the control sample) is attributed to the nonoverlapped light absorption and undisrupted charge transfer rationales. This study presents a proof‐by‐existence that spectrally tailored solar utilization strategy is broadly impactful for the hybrid photothermal–photochemical catalysis. Moreover, the spatially decoupled structural configuration may open up discrete parametric control over photoredox and photoheating functionalities.