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Unveiling Role of Sulfate Ion in Nickel‐Iron (oxy)Hydroxide with Enhanced Oxygen‐Evolving Performance
Author(s) -
Liao Hanxiao,
Luo Tao,
Tan Pengfei,
Chen Kejun,
Lu Lili,
Liu Yong,
Liu Min,
Pan Jun
Publication year - 2021
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.202102772
Subject(s) - oxygen evolution , overpotential , hydroxide , materials science , electrochemistry , catalysis , nickel , electrolyte , thiourea , chemical engineering , inorganic chemistry , leaching (pedology) , electrode , chemistry , metallurgy , organic chemistry , environmental science , soil science , engineering , soil water
The rational design of effective catalysts for sluggish oxygen evolution reactions (OERs) is desired but challenging. Nickel‐iron (NiFe) (oxy)hydroxides are promising pre‐electrocatalysts for alkaline OER. However, OER performances are limited by the slow reconstruction process to generate active species of high‐valance NiFe oxyhydroxides. In this work, a sulfate ion (SO 4 2− ) modulated strategy is developed to boost the OER activity of NiFe (oxy)hydroxide by accelerating the electrochemical reconstruction of pre‐catalyst and stabilizing the reaction intermediate of OOH* during OER. The SO 4 2− decorated NiFe (oxy)hydroxide catalyst (NF‐S0.15) is fabricated via scalable anodization of NiFe foam in a thiourea‐dissolved electrolyte. The experimental and theoretical investigations demonstrate the dual effect of SO 4 2− on improving OER performances. SO 4 2− leaching is favorable for the electrochemical reconstruction to form active NiFeOOH under OER condition. Simultaneously, the residual SO 4 2− adsorbed on surface can stabilize the intermediate of OOH*, and thus enhance the OER performances. As expected, NF‐S0.15 delivers an ultralow overpotential of 234 mV to reach the current density of 50 mA cm −2 , a fast OER kinetics (27.7 mV dec −1 ), and a high stability for more than 100 h. This unique insights into anionic modification could inspire the development of advanced electrocatalysts for efficient OER.