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Self‐Powered Red/UV Narrowband Photodetector by Unbalanced Charge Carrier Transport Strategy
Author(s) -
Hou Yuchen,
Wu Congcong,
Huang Xu,
Yang Dong,
Ye Tao,
Yoon Jungjin,
Sriramdas Rammohan,
Wang Kai,
Priya Shashank
Publication year - 2021
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.202007016
Subject(s) - materials science , photodetector , optoelectronics , quantum efficiency , doping , perovskite (structure) , charge carrier , specific detectivity , dark current , chemical engineering , engineering
Abstract Narrowband photodetector (NB‐PD) with selective light detection is critical for artificial vision and imaging. Intrinsic (optical‐filter‐free) NB‐PDs using conjugated organics or halide perovskite materials have been developed for eliminating the current complex filtering systems in NB‐PDs. However, the poor performance and external driving circuit of organic NB‐PDs as well as complex doping and uncontrollable recombination reactions in typical perovskite NB‐PDs have limited their applicational diversification. A p‐type self‐doped perovskite for intrinsic NB detection is reported which exhibits unique unbalanced electron–hole transfer kinetics. In conjunction with the optical field distribution, an unbalanced charge transport within the self‐doped perovskite triggers a wavelength‐dependent photo‐carrier collection, resulting in a novel spontaneous internal quantum efficiency narrowing mechanism. As a result, by reverting the device architectural polarity, an NB detection at a monochromic light of either red or UV is observed. Using such a revertible asymmetric device design, self‐powered NB‐PDs are successfully achieved. Briefly, the corresponding NB‐PDs exhibit excellent narrow response with a response window of ≈100 nm, high detectivity ≈10 11 Jones, and fast response speed ( f −3dB ≈ 60 kHz) at zero bias. These results demonstrate a new strategy of manipulating internal charge transport to realize power‐free and filter‐free intrinsic NB‐PDs.