Premium
Meeting High Stability and Efficiency in Hybrid Light‐Emitting Diodes Based on SiO 2 /ZrO 2 Coated CsPbBr 3 Perovskite Nanocrystals
Author(s) -
Duan Yanyan,
Ezquerro Cintia,
Serrano Elena,
Lalinde Elena,
GarcíaMartínez Javier,
Berenguer Jesús R.,
Costa Rubén D.
Publication year - 2020
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.202005401
Subject(s) - materials science , perovskite (structure) , diode , oxide , optoelectronics , nanocrystal , nanoparticle , light emitting diode , chemical engineering , photoluminescence , nanometre , coating , nanotechnology , composite material , metallurgy , engineering
Significant advances are realized in perovskite‐converted hybrid light‐emitting diodes (pc‐HLEDs). However, long‐living devices at high efficiencies still represent a major milestone with average stabilities of < 200 h at ≈ 50 lm W −1 under low applied currents ( < 15 mA). Herein, a dual metal oxide‐coated CsPbBr 3 @SiO 2 /ZrO 2 composite is prepared in a one‐pot synthesis through the kinetic control of the sol–gel reaction, followed by a gentle drying process in air. These hybrid nanoparticles show photoluminescence quantum yields of ≈ 65% that are stable under temperature, ambient, and irradiation stress scenarios. This is translated to pc‐HLEDs with a near‐unity conversion efficiency at any applied current, high efficiencies around 75 lm W −1 , and one of the most remarkable stabilities of ≈ 200 and 700 h at 100 and 10 mA, respectively. In addition, the device degradation mechanism is thoughtfully rationalized comparing devices operating under ambient/inert conditions. As such, this work provides three milestones: i) a new room temperature one‐pot protocol to realize the first SiO 2 /ZrO 2 metal oxide coating that effectively protects the emitting perovskite nanoparticle core, ii) one of the most stable and efficient pc‐HLEDs operating under ambient condition at any applied current, and iii) new insights for the degradation of pc‐HLEDs.