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Molecular Functionalization of Chemically Active Defects in WSe 2 for Enhanced Opto‐Electronics
Author(s) -
Zhao Yuda,
Gali Sai Manoj,
Wang Can,
Pershin Anton,
Slassi Amine,
Beljonne David,
Samorì Paolo
Publication year - 2020
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.202005045
Subject(s) - chalcogen , materials science , tungsten diselenide , vacancy defect , monolayer , passivation , surface modification , photoluminescence , nanotechnology , molecular electronics , molecule , optoelectronics , transition metal , chemistry , crystallography , layer (electronics) , catalysis , organic chemistry , biochemistry
Structural defects are known to worsen electrical and optical properties of 2D materials. Transition metal dichalcogenides (TMDs) are prone to chalcogen vacancies and molecular functionalization of these vacancies offers a powerful strategy to engineer the crystal structure by healing such defects. This molecular approach can effectively improve physical properties of 2D materials and optimize the performance of 2D electronic devices. While this strategy has been successfully exploited to heal vacancies in sulfides, its viability on selenides based TMDs has not yet been proven. Here, by using thiophenol molecules to functionalize monolayer WSe 2 surface containing Se vacancies, it is demonstrated that the defect healing via molecular approach not only improves the performance of WSe 2 transistors (> tenfold increase in the current density, the electron mobility, and the I on / I off ratio), but also enhances the photoluminescence properties of monolayer WSe 2 flakes (threefold increase of photoluminescence intensity at room temperature). Theoretical calculations elucidate the mechanism of molecular passivation, which originates from the strong interaction between thiol functional group at Se vacancy sites and neighboring tungsten atoms. These results demonstrate that the molecular approach represents a powerful strategy to engineer WSe 2 transistors and optimize their optical properties, paving the way toward high‐performance 2D (opto)electronic devices.