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The Role of Nanowrinkles in Mass Transport across Graphene‐Based Membranes
Author(s) -
Kang Yuan,
Qiu Ruosang,
Jian Meipeng,
Wang Peiyao,
Xia Yun,
Motevalli Benyamin,
Zhao Wang,
Tian Zhiming,
Liu Jefferson Zhe,
Wang Huanting,
Liu Huiyuan,
Zhang Xiwang
Publication year - 2020
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.202003159
Subject(s) - membrane , graphene , materials science , laminar flow , permeation , mass transport , chemical physics , nanotechnology , wrinkle , chemical engineering , composite material , engineering physics , mechanics , chemistry , physics , biochemistry , engineering
Laminar membranes stacked by 2D materials are an emerging selective unit in separating processes across disciplines for their controllable mass transport properties. In general, parallel nanochannels formed between neighboring layers, owing to their adjustable size and surface chemistry, are considered the dominant transport regulator. Besides these flat interlayer channels, wrinkled morphology has also existed in 2D membranes, but the structure and potential transporting role of such curved channel remain largely unexplored. This study demonstrates that nanowrinkles are intrinsically formed in graphene‐based membranes, featuring an arc‐like shape with around 2.5 nm high center and two narrow wedge corners. By a facile “solvent‐treatment” during assembly, the membranes are tuned to possess different wrinkle density. In transport tests involving water and ions, the appearance of more wrinkles yields higher water permeation yet has limited effect on ion passage. These findings suggest that nanowrinkles by themselves serve as fast transporting ways while their connection with narrow interlayer channels can form a selective network. Results here are expected to deepen the understanding of mass transport mechanisms in current laminar membranes (e.g., graphene‐based) and provide strategies for designing future 2D membranes via wrinkle engineering.