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A One‐Pot Route to Faceted FePt‐Fe 3 O 4 Dumbbells: Probing Morphology–Catalytic Activity Effects in O 2 Reduction Catalysis
Author(s) -
Jenkinson Kellie J.,
Wagner Andreas,
Kornienko Nikolay,
Reisner Erwin,
Wheatley Andrew E. H.
Publication year - 2020
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.202002633
Subject(s) - materials science , catalysis , nanoparticle , dumbbell , facet (psychology) , morphology (biology) , chemical engineering , nanotechnology , organic chemistry , chemistry , medicine , psychology , social psychology , physical therapy , genetics , personality , biology , engineering , big five personality traits
Abstract The design and synthesis of faceted nanoparticles with a controlled composition is of enormous importance to modern catalyst engineering. Faceted FePt‐Fe 3 O 4 dumbbell nanoparticles are prepared by a simple, one‐pot technique that avoids the need for expensive additives or preformed seeds. The faceted product consists of an FePt octopod and a cubic Fe 3 O 4 lobe, of mean diameter 13.6 and 14.9 nm, respectively. The mass normalized activity for electrocatalytic oxygen reduction shows that this new structure types outperforms related catalysts in alkaline media. This work illustrates the power of morphology control and tailoring crystal facet abundance at the nanoparticle surface for enhancing catalytic performance.