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2D Derivative Phase Induced Growth of 3D All Inorganic Perovskite Micro–Nanowire Array Based Photodetectors
Author(s) -
Tong Guoqing,
Jiang Maowei,
Son DaeYong,
Ono Luis K.,
Qi Yabing
Publication year - 2020
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.202002526
Subject(s) - materials science , annealing (glass) , responsivity , photodetector , nanowire , perovskite (structure) , phase transition , recrystallization (geology) , phase (matter) , optoelectronics , grain boundary , nanotechnology , chemical engineering , microstructure , composite material , condensed matter physics , chemistry , physics , organic chemistry , engineering , biology , paleontology
A large number of derivative phases in inorganic perovskites are reported with special structures and extraordinary performances in photoelectronic device applications. The reverse phase transition between derivative phases and perovskites usually induces recrystallization or forms mixed components. In this work, derivative phase‐induced growth of the CsPbBr 3 micro–nanowire (MW) array by utilizing phase transition of the 2D CsPb 2 Br 5 phase is reported. Owing to its layered structure and phase transition, annealing of CsPb 2 Br 5 at a temperature of 550 °C combined with solvent quenching leads to a templating effect to form a high‐quality CsBr MW array. Subsequent PbBr 2 deposition and the second annealing are employed to form aligned CsPbBr 3 MW arrays. Based on this method, a CsPbBr 3 MW array‐based photodetector is fabricated. The large grain size, less grain boundaries, and lower surface potential of the CsPbBr 3 MW array lead to high device performance with a responsivity of 7.66 A W −1 , a detectivity of ≈10 12 Jones, and long‐term operational stability over 1900 min.