Premium
Catalytic Conversion of Polysulfides on Single Atom Zinc Implanted MXene toward High‐Rate Lithium–Sulfur Batteries
Author(s) -
Zhang Di,
Wang Shuai,
Hu Riming,
Gu Jianan,
Cui Yanglansen,
Li Bin,
Chen Weihua,
Liu Chuntai,
Shang Jiaxiang,
Yang Shubin
Publication year - 2020
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.202002471
Subject(s) - sulfur , materials science , cathode , electronegativity , nucleation , catalysis , zinc , lithium (medication) , chemical engineering , redox , inorganic chemistry , chemistry , metallurgy , organic chemistry , medicine , engineering , endocrinology
Although lithium–sulfur (Li–S) batteries are one of the most promising energy storage devices owing to their high energy densities, the sluggish reaction kinetics and severe shuttle effect of the sulfur cathodes hinder their practical applications. Here, single atom zinc implanted MXene is introduced into a sulfur cathode, which can not only catalyze the conversion reactions of polysulfides by decreasing the energy barriers from Li 2 S 4 to Li 2 S 2 /Li 2 S but also achieve strong interaction with polysulfides due to the high electronegativity of atomic zinc on MXene. Moreover, it is found that the homogenously dispersed zinc atoms can also accelerate the nucleation of Li 2 S 2 /Li 2 S on MXene layers during the redox reactions. As a result, the sulfur cathode with single atom zinc implanted MXene exhibits a high reversible capacity of 1136 mAh g −1 . After electrode optimization, a high areal capacity of 5.3 mAh cm −2 , high rate capability of 640 mAh g −1 at 6 C, and good cycle stability (80% capacity retention after 200 cycles at 4 C) can be achieved.