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Interface‐Induced Pseudocapacitance in Nonporous Heterogeneous Particles for High Volumetric Sodium Storage
Author(s) -
Zhao Bo,
Liu Qianqian,
Chen Yujie,
Liu Qian,
Yu Qian,
Wu Hao Bin
Publication year - 2020
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.202002019
Subject(s) - pseudocapacitance , materials science , nanoporous , porous medium , nanotechnology , chemical engineering , energy storage , porosity , electrochemistry , electrode , supercapacitor , composite material , chemistry , engineering , power (physics) , physics , quantum mechanics
Abstract Developing pseudocapacitive materials for electrochemical energy storage generally relies on the formation of nanosize and/or nanoporous particles with short solid‐state diffusion distance and high surface area, which leads to low volumetric capacity and severe parasitic reactions. In this work, nonporous bulky heterogeneous particles composed of TiO 2 matrix and phosphorus are reported for high volumetric pseudocapacitive Na storage. An in situ formed 3D titanium phosphate interphase serves as a fast ionic transport network, allowing rapid sodiation/desodiation processes within the particles. Such nonporous heterogeneous particles exhibit “interface‐induced pseudocapacitance” with an enhanced volumetric capacity, which is over 50% higher than that of commercial hard carbon anodes. This study demonstrates heterogeneous particles with a well‐engineered nanostructure as a new paradigm for electrode materials design.