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Localized Ostwald Ripening Guided Dissolution/Regrowth to Ancient Chinese Coin‐shaped VO 2 Nanoplates with Enhanced Mass Transfer for Zinc Ion Storage
Author(s) -
Cao Ziyi,
Wang Lipeng,
Zhang Hong,
Zhang Xiang,
Liao Jiangwen,
Dong Juncai,
Shi Jiangyue,
Zhuang Peiyuan,
Cao Yudong,
Ye Mingxin,
Shen Jianfeng,
Ajayan Pulickel M.
Publication year - 2020
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.202000472
Subject(s) - ostwald ripening , materials science , dissolution , electrolyte , vanadium , nanostructure , mass transfer , hydrothermal circulation , nanotechnology , electrochemistry , chemical engineering , aqueous solution , electrode , metallurgy , chemistry , physics , engineering , thermodynamics
Abstract Charge and mass transfer at the interface between electrode and electrolyte are of vital significance for energy conversion and storage in aqueous rechargeable zinc ion batteries (ZIBs). Approaching rational design and preparation of unique nanostructures with enhanced mass transfer is still facing great challenges in response to these problems. Herein, the highly uniform and round new‐state nsutite‐type vanadium dioxide (VO 2 ) nanoplates with novel ancient Chinese coin structure (with thickness of ≈50 nm and diameter of ≈500 nm, with a hole in the middle) are prepared successfully. During the hydrothermal process, the VO 2 nanoplate undergoes an interesting Ostwald ripening guided dissolution‐regrowth process, resulting in the formation of the unusual ancient Chinese coin structure. Impressively, based on structural merits of the abundant electrolyte‐accessible sites and transfer pathways, the mass transfer can be enhanced at the surface of as‐prepared VO 2 nanoplates‐based electrode. The VO 2 nanoplates further deliver high reversible specific capacity and rate ability for rechargeable ZIBs. Hence, this work presents a new avenue for designing unique nanostructure vanadium oxides to boost the electrochemical properties of aqueous ZIBs.