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Asymmetric Acceptors with Fluorine and Chlorine Substitution for Organic Solar Cells toward 16.83% Efficiency
Author(s) -
Liu Tao,
Zhang Youdi,
Shao Yiming,
Ma Ruijie,
Luo Zhenghui,
Xiao Yiqun,
Yang Tao,
Lu Xinhui,
Yuan Zhongyi,
Yan He,
Chen Yiwang,
Li Yongfang
Publication year - 2020
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.202000456
Subject(s) - organic solar cell , fluorine , materials science , homo/lumo , small molecule , energy conversion efficiency , chlorine , open circuit voltage , molecule , photovoltaic system , atom (system on chip) , yield (engineering) , voltage , optoelectronics , chemistry , organic chemistry , physics , electrical engineering , polymer , computer science , metallurgy , composite material , engineering , biochemistry , quantum mechanics , embedded system
Small‐molecule acceptors (SMAs)‐based organic solar cells (OSCs) have exhibited great potential for achieving high power conversion efficiencies (PCEs). Meanwhile, developing asymmetric SMAs to improve photovoltaic performance by modulating energy level distribution and morphology has drawn lots of attention. In this work, based on the high‐performance SMA (Y6), three asymmetric SMAs are developed by substituting the fluorine atoms on the terminal group with chlorine atoms, namely SY1 (two F atoms and one Cl atom), SY2 (two F atoms and two Cl atoms), and SY3 (three Cl atoms). Y6 (four F atoms) and Y6‐4Cl (four Cl atoms) are synthesized as control molecules. As a result, SY1 exhibits the shallowest lowest unoccupied molecular orbital energy level and the best molecular packing among these five acceptors. Consequently, OSCs based on PM6:SY1 yield a champion PCE of 16.83% with an open‐circuit voltage ( V OC ) of 0.871 V, and a fill factor (FF) of 0.760, which is the best result among the five devices. The highest FF for the PM6:SY1‐based device is mainly ascribed to the most balanced charge transport and optimal morphology. This contribution provides deeper understanding of applying asymmetric molecule design method to further promote PCEs of OSCs.