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The Interplay between Surface Plasmon Resonance and Switching Properties in Gold@Spin Crossover Nanocomposites
Author(s) -
Palluel Marlène,
Tran Ngoc Minh,
Daro Nathalie,
Buffière Sonia,
Mornet Stéphane,
Freysz Eric,
Chastanet Guillaume
Publication year - 2020
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.202000447
Subject(s) - nanorod , surface plasmon resonance , materials science , plasmon , nanoparticle , photothermal therapy , spin crossover , nanotechnology , resonance (particle physics) , nanostructure , dielectric , surface plasmon , photothermal effect , nanocomposite , localized surface plasmon , optoelectronics , chemistry , crystallography , physics , particle physics
Rod‐like gold nanoparticles are directly embedded in a 1D‐polymeric spin crossover (SCO) material leading to singular Au@SCO nanohybrid architectures. The resulting architectures are designed to promote a synergetic effect between ultrafast spin‐state photoswitching and photothermal properties of plasmonic nanoparticles. This synergy is evidenced by the strong modulation of the surface plasmon resonance of the gold nanorods through the spin‐state switching of the SCO component and also the strong enhancement of the photoswitching efficiency compared to pure SCO particles. This remarkable synergy results from the large modulation of the dielectric properties of the SCO polymer upon its thermal switching and the enhancement of the heating of these hybrid nanostructures upon excitation of the surface plasmon resonance of the gold nanorods.