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Electrocatalysis: Exfoliated Layered Manganese Trichalcogenide Phosphite (MnP X 3 , X = S, Se) as Electrocatalytic van der Waals Materials for Hydrogen Evolution (Adv. Funct. Mater. 2/2019)
Author(s) -
Gusmão Rui,
Sofer Zdeněk,
Pumera Martin
Publication year - 2019
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.201970008
Subject(s) - exfoliation joint , electrocatalyst , van der waals force , materials science , manganese , hydrogen , delamination (geology) , chemical engineering , nanotechnology , metallurgy , chemistry , electrochemistry , organic chemistry , electrode , graphene , engineering , molecule , paleontology , biology , subduction , tectonics
Peel it and see: 2D‐layered manganese chalcogenophosphites, MnP X 3 ( X = S, Se), are synthetized and submitted to shear force exfoliation. The process, described by Martin Pumera and co‐workers in article number 1805975 , causes MP X 3 to undergo downsizing, alongside with delamination. Layered exfoliated MnPSe 3 has the lowest onset potential for the hydrogen evolution reaction and good stability. Such exfoliated MnP X 3 shows great promise in a future hydrogen‐based economy.

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