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Interface Engineering by Thiazolium Iodide Passivation Towards Reduced Thermal Diffusion and Performance Improvement in Perovskite Solar Cells
Author(s) -
Salado Manuel,
Andresini Michael,
Huang Peng,
Khan Mohd Taukeer,
Ciriaco Fulvio,
Kazim Samrana,
Ahmad Shahzada
Publication year - 2020
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.201910561
Subject(s) - passivation , materials science , perovskite (structure) , fabrication , iodide , thermal stability , diffusion , energy conversion efficiency , degradation (telecommunications) , chemical engineering , nanotechnology , layer (electronics) , optoelectronics , inorganic chemistry , electronic engineering , medicine , chemistry , alternative medicine , physics , pathology , engineering , thermodynamics
Interface engineering has become one of the most facile and effective approaches to improve solar cells performance and its long‐term stability and to retard unwanted side reactions. Three passivating agents are developed which can functionalize the surface and induce hydrophobicity, by employing substituted thiazolium iodide (TMI) for perovskite solar cells fabrication. The role of TMI interfacial layers in microstructure and electro‐optical properties is assessed for structural as well as transient absorption measurements. TMI treatment resulted in V OC and fill factor enhancement by reducing possible recombination paths at the perovskite/hole selective interface and by reducing the shallow as well as deep traps. These in turn allow to achieve higher performance as compared to the pristine surface. Additionally, the TMI passivated perovskite layer considerably reduces CH 3 NH 3 + thermal diffusion and degradation induced by humidity. The un‐encapsulated perovskite solar cells employing TMI exhibit a remarkable stability under moisture levels (≈50% RH), retaining ≈95% of the initial photon current efficiency after 800 h of fabrication, paving the way towards a potential scalable endeavor.