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Functional Coatings on High‐Performance Polymer Fibers for Smart Sensing
Author(s) -
Galinski Henning,
Leutenegger Daniel,
Amberg Martin,
Krogh Fabio,
Schnabel Volker,
Heuberger Manfred,
Spolenak Ralph,
Hegemann Dirk
Publication year - 2020
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.201910555
Subject(s) - materials science , polyester , polyethylene terephthalate , thermochromism , composite material , polymer , coating , chalcogenide , thermal , phase transition , optoelectronics , chemistry , physics , organic chemistry , quantum mechanics , meteorology
Above a critical temperature, high‐performance fibers may lose their mechanical properties resulting in catastrophic events of damage when, e.g., used as load‐carrying ropes. Here, a method to functionalize polymer fibers with thermochromic optical coatings that enable signaling of damaging thermal history is introduced. These smart coatings are comprised of an index‐tunable anti‐reflection coating based on chalcogenide phase change materials (PCM). It is demonstrated that the insulator−metal phase transition of these materials can be aligned with the critical deterioration temperature of both polyethylene terephthalate (PET) monofilaments and liquid‐crystal polyester (LCP) yarns by composition tuning. The carefully designed optical system amplifies the change in optical properties of its constituents upon phase change. The thermal and mechanical degradation of these fibers can thus be monitored and displayed by eye.