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Robust Design of Dual‐Phasic Carbon Cathode for Lithium–Oxygen Batteries
Author(s) -
Pham Hien Thi Thu,
Kim Yeongsu,
Kim YoungJun,
Lee JongWon,
Park MinSik
Publication year - 2019
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.201902915
Subject(s) - materials science , cathode , electrochemistry , carbon fibers , porosity , lithium (medication) , carbon nanotube , battery (electricity) , nanotechnology , chemical engineering , oxygen , electrode , composite material , electrical engineering , organic chemistry , medicine , power (physics) , chemistry , physics , quantum mechanics , endocrinology , composite number , engineering
Abstract Given that the performance of a lithium–oxygen battery (LOB) is determined by the electrochemical reactions occurring on the cathode, the development of advanced cathode nanoarchitectures is of great importance for the realization of high‐energy‐density, reversible LOBs. Herein, a robust cathode design is proposed for LOBs based on a dual‐phasic carbon nanoarchitecture. The cathode is composed of an interwoven network of porous metal–organic framework (MOF) derived carbon (MOF‐C) and conductive carbon nanotubes (CNTs). The dual‐phasic nanoarchitecture incorporates the advantages of both components: MOF‐C provides a large surface area for the oxygen reactions and a large pore volume for Li 2 O 2 storage, and CNTs provide facile pathways for electron and O 2 transport as well as additional void spaces for Li 2 O 2 accommodation. It is demonstrated that the synergistic nanoarchitecturing of the dual‐phasic MOF‐C/CNT material results in promising electrochemical performance of LOBs, as evidenced by a high discharge capacity of ≈10 050 mAh g −1 and a stable cycling performance over 75 cycles.