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Suppressing Manganese Dissolution in Potassium Manganate with Rich Oxygen Defects Engaged High‐Energy‐Density and Durable Aqueous Zinc‐Ion Battery
Author(s) -
Fang Guozhao,
Zhu Chuyu,
Chen Minghui,
Zhou Jiang,
Tang Boya,
Cao Xinxin,
Zheng Xusheng,
Pan Anqiang,
Liang Shuquan
Publication year - 2019
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.201808375
Subject(s) - dissolution , manganese , materials science , cathode , aqueous solution , inorganic chemistry , battery (electricity) , chemical engineering , oxygen , ion , manganate , activation energy , metallurgy , chemistry , organic chemistry , thermodynamics , physics , engineering , power (physics)
The manganese dissolution leading to sharp capacity decline as well as the sluggish reaction kinetic are still major issues for manganese‐based materials as aqueous zinc‐ion batteries (ZIBs) cathodes. Here, a potassium‐ion‐stabilized and oxygen‐defect K 0.8 Mn 8 O 16 is reported as a high‐energy‐density and durable cathode for neutral aqueous ZIBs. A new insight into suppressing manganese dissolution via incorporation of K + ions to intrinsically stabilize the Mn‐based cathodes is provided. A comprehensive study suggests that oxygen defects improve electrical conductivity and open the MnO 6 polyhedron walls for ion diffusion, which plays a critical role in the fast reaction kinetics and capacity improvement of K 0.8 Mn 8 O 16 . In addition, direct evidence for the mechanistic details of simultaneous insertion and conversion reaction based on H + ‐storage mechanism is demonstrated. As expected, a significant energy output of 398 W h kg −1 (based on the mass of cathode) and an impressive durability over 1000 cycles with no obvious capacity fading are obtained. Such a high‐energy Zn‐K 0.8 Mn 8 O 16 battery, as well as the basic understanding of manganese dissolution and oxygen defects may open new opportunities toward high‐performance aqueous ZIBs.