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Electrochemical Mechanism Investigation of Cu 2 MoS 4 Hollow Nanospheres for Fast and Stable Sodium Ion Storage
Author(s) -
Chen Jingwei,
Mohrhusen Lars,
Ali Ghulam,
Li Shaohui,
Chung Kyung Yoon,
AlShamery Katharina,
Lee Pooi See
Publication year - 2019
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.201807753
Subject(s) - materials science , electrochemistry , electrolyte , chemical engineering , x ray photoelectron spectroscopy , graphene , anode , lithium (medication) , cathode , oxide , sulfide , electrode , nanotechnology , metallurgy , medicine , chemistry , endocrinology , engineering
Sodium ion batteries (SIBs) are promising alternatives to lithium ion batteries with advantages of cost effectiveness. Metal sulfides as emerging SIB anodes have relatively high electronic conductivity and high theoretical capacity, however, large volume change during electrochemical testing often leads to unsatisfactory electrochemical performance. Herein bimetallic sulfide Cu 2 MoS 4 (CMS) with layered crystal structures are prepared with glucose addition (CMS1), resulting in the formation of hollow nanospheres that endow large interlayer spacing, benefitting the rate performance and cycling stability. The electrochemical mechanisms of CMS1 are investigated using ex situ X‐ray photoelectron spectroscopy and in situ X‐ray absorption spectroscopy, revealing the conversion‐based mechanism in carbonate electrolyte and intercalation‐based mechanism in ether‐electrolyte, thus allowing fast and reversible Na + storage. With further introduction of reduced graphene oxide (rGO), CMS1–rGO composites are obtained, maintaining the hollow structure of CMS1. CMS1–rGO delivers excellent rate performance (258 mAh g −1 at 50 mA g −1 and 131.9 mAh g −1 at 5000 mA g −1 ) and notably enhanced cycling stability (95.6% after 2000 cycles). A full cell SIB is assembled by coupling CMS1–rGO with Na 3 V 2 (PO 4 ) 3 ‐based cathode, delivering excellent cycling stability (75.5% after 500 cycles). The excellent rate performance and cycling stability emphasize the advantage of CMS1–rGO toward advanced SIB full cells assembly.