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Molybdenum Oxide Nanosheets with Tunable Plasmonic Resonance: Aqueous Exfoliation Synthesis and Charge Storage Applications
Author(s) -
Etman Ahmed S.,
Wang Ligang,
Edström Kristina,
Nyholm Leif,
Sun Junliang
Publication year - 2019
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.201806699
Subject(s) - materials science , exfoliation joint , surface plasmon resonance , molybdenum , electrolyte , electrode , aqueous solution , electrochemistry , oxide , chemical engineering , nanotechnology , molybdenum disulfide , nanoparticle , graphene , composite material , organic chemistry , chemistry , engineering , metallurgy
Herein, a simple aqueous‐exfoliation strategy is introduced for the fabrication of a series of MoO 3− x nanosheets (where x stands for oxygen vacancies) using two commercial molybdenum oxide precursors, MoO 2 and MoO 3 . The nanosheets offer a localized surface plasmon resonance (LSPR) effect which is dependent on the structure and local environment of the nanosheets. The LSPR can be efficiently tuned by changing the weight ratio between the molybdenum oxide precursor(s) and/or by solar light irradiation using a low‐energy UV lamp (36 W). For the pristine MoO 3− x nanosheets, the highest LSPR signal is obtained for nanosheets prepared using 80% MoO 2 . On the contrary, after solar light irradiation, the nanosheets prepared using pure MoO 3 offer the highest LSPR response. The nanosheets also show an outstanding rate capability when used as binder‐free supercapacitor electrodes in an acidified Na 2 SO 4 electrolyte. The electrodes exhibit discharge capacities of 110 and 75 C g −1 at a scan rate of 20 and 1000 mV s −1 , respectively. The MoO 3− x nanosheets can likewise be used as a negative electrode material for lithium‐ion batteries. The efficient eco‐friendly synthesis and the ability to tune the photochemical and electrochemical properties of the nanosheets make this approach interesting to many energy‐related research fields.