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3D‐Printed MOF‐Derived Hierarchically Porous Frameworks for Practical High‐Energy Density Li–O 2 Batteries
Author(s) -
Lyu Zhiyang,
Lim Gwendolyn J. H.,
Guo Rui,
Kou Zongkui,
Wang Tingting,
Guan Cao,
Ding Jun,
Chen Wei,
Wang John
Publication year - 2019
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.201806658
Subject(s) - materials science , porosity , cathode , metal organic framework , chemical engineering , nanotechnology , nanoparticle , energy storage , porous medium , annealing (glass) , carbon fibers , composite material , adsorption , organic chemistry , power (physics) , chemistry , physics , quantum mechanics , composite number , engineering
Aprotic Li–O 2 batteries are promising candidates for next‐generation energy storage technologies owing to their high theoretical energy densities. However, their practically achievable specific energy is largely limited by the need for porous conducting matrices as cathode support and the passivation of cathode surface by the insulating Li 2 O 2 product. Herein, a self‐standing and hierarchically porous carbon framework is reported with Co nanoparticles embedded within developed by 3D‐printing of cobalt‐based metal–organic framework (Co‐MOF) using an extrusion‐based printer, followed by appropriate annealing. The novel self‐standing framework possesses good conductivity and necessary mechanical stability, so that it can act as a porous conducting matrix. Moreover, the porous framework consists of abundant micrometer‐sized pores formed between Co‐MOF‐derived carbon flakes and meso‐ and micropores formed within the flakes, which together significantly benefit the efficient deposition of Li 2 O 2 particles and facilitate their decomposition due to the confinement of insulating Li 2 O 2 within the pores and the presence of Co electrocatalysts. Therefore, the self‐standing porous architecture significantly enhances the cell's practical specific energy, achieving a high value of 798 Wh kg −1 cell . This study provides an effective approach to increase the practical specific energy for Li–O 2 batteries by constructing 3D‐printed framework cathodes.