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VO x @MoO 3 Nanorod Composite for High‐Performance Supercapacitors
Author(s) -
Wang SiQi,
Cai Xiang,
Song Yu,
Sun Xiaoqi,
Liu XiaoXia
Publication year - 2018
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.201803901
Subject(s) - materials science , supercapacitor , capacitance , electrode , dielectric spectroscopy , x ray photoelectron spectroscopy , composite number , electrochemistry , nanorod , fourier transform infrared spectroscopy , chemical engineering , nanotechnology , optoelectronics , composite material , chemistry , engineering
Vanadium oxide is a promising pseudocapacitive electrode, but their capacitance, especially at high current densities, requires improvement for practical applications. Herein, a VO x @MoO 3 composite electrode is constructed through a facile electrochemical method. Fourier transform infrared spectroscopy and X‐ray photoelectron spectroscopy demonstrate a modification on the chemical environment and electronic structure of VO x upon the effective interaction with the thin layer of MoO 3 . A careful investigation of the electrochemical impedance spectroscopy data reveals much enhanced power capability of the composite electrode. More charge storage sites will also be created at/near the heterogeneous interface. Due to those synergistic effects, the VO x @MoO 3 electrode shows excellent electrochemical performance. It provides a high capacitance of 1980 mF cm −2 at 2 mA cm −2 . Even at the high current density of 100 mA cm −2 , it still achieves 1166 mF cm −2 capacitance, which doubles the sum of single electrodes. The MoO 3 layer also helps to prevent VO x structure deformation, and 94% capacitance retention over 10 000 cycles is obtained for the composite electrode. This work demonstrates an effective strategy to induce interactions between heterogeneous components and enhance the electrochemical performance, which can also be applied to other pseudocapacitive electrode candidates.