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Atomically Thin Defect‐Rich Fe–Mn–O Hybrid Nanosheets as High Efficient Electrocatalyst for Water Oxidation
Author(s) -
Teng Yuan,
Wang XuDong,
Liao JinFeng,
Li WenGuang,
Chen HongYan,
Dong YuJie,
Kuang DaiBin
Publication year - 2018
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.201802463
Subject(s) - nanosheet , materials science , tafel equation , oxygen evolution , electrocatalyst , overpotential , catalysis , chemical engineering , water splitting , crystallinity , calcination , oxide , nanotechnology , electrode , electrochemistry , metallurgy , composite material , chemistry , photocatalysis , engineering , biochemistry
Engineering non‐noble metal–based electrocatalysts with superior water oxidation performance is highly desirable for the production of renewable chemical fuels. Here, an atomically thin low‐crystallinity Fe–Mn–O hybrid nanosheet grown on carbon cloth (Fe–Mn–O NS/CC) is successfully synthetized as an efficient oxygen evolution reaction (OER) catalyst. The synthesis strategy involves a facile reflux reaction and subsequent low‐temperature calcination process, and the morphology and composition of hybrid nanosheets can be tailored conveniently. The defect‐rich Fe–Mn–O ultrathin nanosheet with uniform element distribution enables exposure of more catalytic active sites; moreover, the atomic‐scale synergistic action of Mn and Fe oxide contributes to an enhanced intrinsic catalytic activity. Therefore, the optimized Fe–Mn–O hybrid nanosheets, with lateral sizes of about 100–600 nm and ≈1.4 nm in thickness, enable a low onset potential of 1.46 V, low overpotential of 273 mV for current density of 10 mA cm −2 , a small Tafel slope of 63.9 mV dec −1 , and superior durability, which are superior to that of individual MnO 2 and FeOOH electrode, and even outperforming most reported MnO 2 ‐based electrocatalysts.