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Ternary Emission of Fluorescence and Dual Phosphorescence at Room Temperature: A Single‐Molecule White Light Emitter Based on Pure Organic Aza‐Aromatic Material
Author(s) -
Zhou Changjiang,
Zhang Shitong,
Gao Yu,
Liu Haichao,
Shan Tong,
Liang Xiaoming,
Yang Bing,
Ma Yuguang
Publication year - 2018
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.201802407
Subject(s) - phosphorescence , fluorescence , materials science , ternary operation , molecule , common emitter , excited state , oled , phenazine , luminescence , photochemistry , optoelectronics , nanotechnology , atomic physics , optics , chemistry , organic chemistry , physics , layer (electronics) , computer science , programming language
Herein, a simple aza‐aromatic compound dibenzo[a,c]phenazine (DPPZ), which exhibits single‐molecule white light with a ternary emission, consisting of simultaneous fluorescence (S 1 →S 0 ) and dual room‐temperature phosphorescence (RTP, T 2 →S 0 and T 1 →S 0 ) is reported. The Commission Internationale de l' Éclairage coordinates of DPPZ powder are (0.28, 0.33). To everyone's knowledge, this is the first case to achieve single‐molecule white emission with ternary emission of fluorescence and dual RTP. This finding provides a prototype strategy to realize low‐cost, stable pure organic single‐molecule white light emission with three standard primary colors through further precise modulation of excited states.