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Nickel@Nickel Oxide Core–Shell Electrode with Significantly Boosted Reactivity for Ultrahigh‐Energy and Stable Aqueous Ni–Zn Battery
Author(s) -
Wang Rui,
Han Yi,
Wang Zifan,
Jiang Jiuxing,
Tong Yexiang,
Lu Xihong
Publication year - 2018
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.201802157
Subject(s) - materials science , battery (electricity) , non blocking i/o , cathode , aqueous solution , energy storage , electrode , electrochemistry , nickel , power density , chemical engineering , alkaline battery , oxide , nickel oxide , nanotechnology , metallurgy , power (physics) , catalysis , chemistry , biochemistry , physics , quantum mechanics , engineering
The main bottlenecks of aqueous rechargeable Ni–Zn batteries are their relatively low energy density and poor cycling stability, mainly arising from the low capacity and inferior reversibility of the current Ni‐based cathodes. Additionally, the complicated and difficult‐to‐scale preparation procedures of these cathodes are not promising for large‐scale energy storage. Here, a facile and cost‐effective ultrasonic‐assisted strategy is developed to efficiently activate commercial Ni foam as a robust cathode for a high‐energy and stable aqueous rechargeable Ni–Zn battery. 3D Ni@NiO core–shell electrode with remarkably boosted reactivity and an area of 300 cm 2 is readily obtained by this ultrasonic‐assisted activation method (denoted as SANF). Benefiting from the in situ formation of electrochemically active NiO and porous 3D structure with a large surface area, the as‐fabricated SANF//Zn battery presents ultrahigh capacity (0.422 mA h cm −2 ) and excellent cycling durability (92.5% after 1800 cycles). Moreover, this aqueous rechargeable SANF//Zn battery achieves an impressive energy density of 15.1 mW h cm −3 (0.754 mW h cm −2 ) and a peak power density of 1392 mW cm −3 , outperforming most reported aqueous rechargeable energy‐storage devices. These findings may provide valuable insights into designing large‐scale and high‐performance 3D electrodes for aqueous rechargeable batteries.