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Finely Crafted 3D Electrodes for Dendrite‐Free and High‐Performance Flexible Fiber‐Shaped Zn–Co Batteries
Author(s) -
Li Ming,
Meng Jiashen,
Li Qi,
Huang Meng,
Liu Xiong,
Owusu Kwadwo Asare,
Liu Ziang,
Mai Liqiang
Publication year - 2018
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.201802016
Subject(s) - materials science , anode , cathode , power density , battery (electricity) , electrolyte , energy storage , electrode , zeolitic imidazolate framework , chemical engineering , electrochemistry , dendrite (mathematics) , nanorod , fiber , nanotechnology , composite material , power (physics) , metal organic framework , electrical engineering , physics , organic chemistry , quantum mechanics , adsorption , engineering , chemistry , geometry , mathematics
Abstract Rechargeable aqueous Zn‐based batteries, benefiting from their good reliability, low cost, high energy/power densities, and ecofriendliness, show great potential in energy storage systems. However, the poor cycling performance due to the formation of Zn dendrites greatly hinders their practical applications. In this work, a trilayer 3D CC‐ZnO@C‐Zn anode is obtained by in situ growing ZIFs (zeolitic‐imidazolate frameworks) derived ZnO@C core–shell nanorods on carbon cloth followed by Zn deposition, which exhibits excellent antidendrite performance. Using CC‐ZnO@C‐Zn as the anode and a branch‐like Co(CO 3 ) 0.5 (OH) x ·0.11H 2 O@CoMoO 4 (CC‐CCH@CMO) as the cathode, a Zn–Co battery is rationally designed, displaying excellent energy/power densities (235 Wh kg −1 , 12.6 kW kg −1 ) and remarkable cycling performance (71.1% after 5000 cycles). Impressively, when using a gel electrolyte, a highly customizable, fiber‐shaped flexible all‐solid‐state Zn–Co battery is assembled for the first time, which presents a high energy density of 4.6 mWh cm −3 , peak power density of 0.42 W cm −3 , and long durability (82% capacity retention after 1600 cycles) as well as excellent flexibility. The unique 3D electrode design in this study provides a novel approach to achieve high‐performance Zn‐based batteries, showing promising applications in flexible and portable energy‐storage systems.