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Ternary Blend Strategy for Achieving High‐Efficiency Organic Solar Cells with Nonfullerene Acceptors Involved
Author(s) -
Liu Xiaoyu,
Yan Yajie,
Yao Yao,
Liang Ziqi
Publication year - 2018
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.201802004
Subject(s) - organic solar cell , ternary operation , materials science , tandem , photovoltaic system , acceptor , energy conversion efficiency , polymer solar cell , context (archaeology) , nanotechnology , optoelectronics , computer science , polymer , electrical engineering , physics , composite material , biology , programming language , engineering , paleontology , condensed matter physics
Abstract Nonfullerene acceptors have recently drawn considerable attention in bulk heterojunction organic solar cells (OSCs). The power conversion efficiency (PCE) over 14% is achieved in single‐junction fullerene‐free OSCs, which has surpassed that of fullerene‐based counterparts. For future commercial applications, however, a high and stable PCE > 15% is required, which entails rational material design and device optimization. In this context, three approaches are generally utilized—the synthesis of novel nonfullerene acceptors and the selection of suitable polymer donors to pair with them, the tandem or multijunction device architecture, and the ternary blend strategy. Compared to the former two methods, the ternary strategy allows to employ the existing photovoltaic materials and the single‐junction device. Therefore, an exploration of nonfullerene acceptor–based ternary blend OSCs (NFTSCs) has shown unprecedented progress since 2016. This review summarizes and classifies the photovoltaic materials utilized in NFTSCs, aiming to not only exhibit the recent development of NFTSCs but also elucidate the correlation among donor/acceptor materials, film morphology, transport dynamics, and device fabrication toward high‐efficiency OSCs. Lastly, the above key advances are highlighted along with the existing issues and insights into the viable path for the further research thrusts are offered.