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Layer‐by‐Layer Synthesis of Thick Mesoporous TiO 2 Films with Vertically Oriented Accessible Nanopores and Their Application for Lithium‐Ion Battery Negative Electrodes
Author(s) -
Nagpure Suraj,
Zhang Qinglin,
Khan M. Arif,
Islam Syed Z.,
Xu Jiagang,
Strzalka Joseph,
Cheng YangTse,
Knutson Barbara L.,
Rankin Stephen E.
Publication year - 2018
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.201801849
Subject(s) - materials science , nanopore , mesoporous material , anatase , amorphous solid , chemical engineering , substrate (aquarium) , nanotechnology , layer (electronics) , lithium (medication) , thin film , scanning electron microscope , nanocrystalline material , electrode , composite material , crystallography , medicine , biochemistry , chemistry , oceanography , photocatalysis , endocrinology , geology , engineering , catalysis
TiO 2 films of varying thicknesses (up to ≈1.0 µm) with vertically oriented, accessible 7–9 nm nanopores are synthesized using an evaporation‐induced self‐assembly layer‐by‐layer technique. The hypothesis behind the approach is that epitaxial alignment of hydrophobic blocks of surfactant templates induces a consistent, accessible mesophase orientation across a multilayer film, ultimately leading to continuous, vertically aligned pore channels. Characterization using grazing incidence X‐ray scattering, scanning electron microscopy, and impedance spectroscopy indicates that the pores are oriented vertically even in relatively thick films (up to 1 µm). These films contain a combination of amorphous and nanocrystalline anatase titania of value for electrochemical energy storage. When applied as negative electrodes in lithium‐ion batteries, a capacity of 254 mAh g −1 is obtained after 200 cycles for a single‐layer TiO 2 film prepared on modified substrate, higher than on unmodified substrate or nonporous TiO 2 film, due to the high accessibility of the vertically oriented channels in the films. Thicker films on modified substrate have increased absolute capacity because of higher mass loading but a reduced specific capacity because of transport limitations. These results suggest that the multilayer epitaxial approach is a viable way to prepare high capacity TiO 2 films with vertically oriented continuous nanopores.