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Direct Photomodification of Polymer Surfaces: Unleashing the Potential of Aryl‐Azide Copolymers
Author(s) -
Schulz Anita,
Stocco Antonio,
Bethry Audrey,
Lavigne JeanPhilippe,
Coudane Jean,
Nottelet Benjamin
Publication year - 2018
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.201800976
Subject(s) - copolymer , materials science , azide , photografting , polymer , grafting , biofilm , substrate (aquarium) , polymer chemistry , aryl , oxazoline , biointerface , polymerization , combinatorial chemistry , chemical engineering , nanotechnology , chemistry , organic chemistry , catalysis , alkyl , oceanography , biology , bacteria , composite material , genetics , geology , engineering
The possibility to impart surface properties to any polymeric substrate using a fast, reproducible, and industrially friendly procedure, without the need for surface pretreatment, is highly sought after. This is in particular true in the frame of antibacterial surfaces to hinder the threat of biofilm formation. In this study, the potential of aryl‐azide polymers for photofunctionalization and the importance of the polymer structure for an efficient grafting are demonstrated. The strategy is illustrated with a UV‐reactive hydrophilic poly(2‐oxazoline) based copolymer, which can be photografted onto any polymer substrate that contains carbon–hydrogen bonds to introduce antifouling properties. Through detailed characterization it is demonstrated that the controlled spatial distribution of the UV‐reactive aryl‐azide moieties within the poly(2‐oxazline) structure, in the form of pseudogradient copolymers, ensures higher grafting efficacy than other copolymer structures including block copolymers. Furthermore, it is found that the photografting results in a covalently bound layer, which is thermally stable and causes a significant antiadherence effect and biofilm reduction against Escherichia coli and Staphylococcus epidermidis strains while remaining noncytotoxic against mouse fibroblasts.