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Layered P2‐Type K 0.65 Fe 0.5 Mn 0.5 O 2 Microspheres as Superior Cathode for High‐Energy Potassium‐Ion Batteries
Author(s) -
Deng Tao,
Fan Xiulin,
Chen Ji,
Chen Long,
Luo Chao,
Zhou Xiuquan,
Yang Junhe,
Zheng Shiyou,
Wang Chunsheng
Publication year - 2018
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.201800219
Subject(s) - materials science , cathode , anode , electrolyte , energy storage , intercalation (chemistry) , nanoparticle , chemical engineering , lithium (medication) , potassium , electrochemistry , electrode , nanotechnology , inorganic chemistry , metallurgy , chemistry , medicine , power (physics) , physics , quantum mechanics , endocrinology , engineering
Potassium‐ion batteries have been regarded as the potential alternatives to lithium‐ion batteries (LIBs) due to the low cost, earth abundance, and low potential of K (−2.936 vs standard hydrogen electrode (SHE)). However, the lack of low‐cost cathodes with high energy density and long cycle life always limits its application. In this work, high‐energy layered P2‐type hierarchical K 0.65 Fe 0.5 Mn 0.5 O 2 (P2‐KFMO) microspheres, assembled by the primary nanoparticles, are fabricated via a modified solvent‐thermal method. Benefiting from the unique microspheres with primary nanoparticles, the K + intercalation/deintercalation kinetics of P2‐KFMO is greatly enhanced with a stabilized cathodic electrolyte interphase on the cathode. The P2‐KFMO microsphere presents a highly reversible potassium storage capacity of 151 mAh g −1 at 20 mA g −1 , fast rate capability of 103 mAh g −1 at 100 mA g −1 , and long cycling stability with 78% capacity retention after 350 cycles. A full cell with P2‐KFMO microspheres as cathode and hard carbon as anode is constructed, which exhibits long‐term cycling stability (>80% of retention after 100 cycles). The present high‐performance P2‐KFMO microsphere cathode synthesized using earth‐abundant elements provides a new cost‐effective alternative to LIBs for large‐scale energy storage.