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Highly Efficient Circularly Polarized Electroluminescence from Aggregation‐Induced Emission Luminogens with Amplified Chirality and Delayed Fluorescence
Author(s) -
Song Fengyan,
Xu Zeng,
Zhang Qiushuo,
Zhao Zheng,
Zhang Haoke,
Zhao Weijun,
Qiu Zijie,
Qi Chunxuan,
Zhang Han,
Sung Herman H. Y.,
Williams Ian D.,
Lam Jacky W. Y.,
Zhao Zujin,
Qin Anjun,
Ma Dongge,
Tang Ben Zhong
Publication year - 2018
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.201800051
Subject(s) - electroluminescence , materials science , quantum efficiency , oled , fluorescence , luminescence , optoelectronics , intramolecular force , molecule , photochemistry , chirality (physics) , doping , circular polarization , aggregation induced emission , optics , nanotechnology , chemistry , organic chemistry , physics , chiral symmetry breaking , layer (electronics) , quantum mechanics , quark , nambu–jona lasinio model , microstrip
Development of highly efficient circularly polarized organic light‐emitting diodes (CPOLEDs) has gained increasing interest as they show improved luminous efficiency and high contract 3D images in OLED displays. In this work, a series of binaphthalene‐containing luminogenic enantiomers with aggregation‐induced emission (AIE) and delayed fluorescence properties is designed and synthesized. These molecules can emit from green to red light depending on the solvent polarity due to the twisted intramolecular charge transfer effect. However, their solid powders show bright light emissions, demonstrating a phenomenon of AIE. All the molecules exhibit Cotton effects and circularly polarized luminescence in toluene solution and films. Multilayer CPOLEDs using the doped and neat films of the molecules as emitting layers are fabricated, which exhibit high external quantum efficiency of up to 9.3% and 3.5% and electroluminescence dissymmetry factor ( g EL ) of up to +0.026/−0.021 and +0.06/−0.06, respectively. Compared with doped CPOLEDs, the nondoped ones show higher g EL and much smaller current efficiency roll‐off due to the stronger AIE effect. By altering the donor unit, the electroluminescence maximum of the doped film can vary from 493 to 571 nm. As far as it is known, this is the first example of efficient CPOLEDs based on small chiral organic molecules.