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Rationalizing Fabrication and Design Toward Highly Efficient and Stable Blue Light‐Emitting Electrochemical Cells Based on NHC Copper(I) Complexes
Author(s) -
Weber Michael D.,
Fresta Elisa,
Elie Margaux,
Miehlich Matthias E.,
Renaud JeanLuc,
Meyer Karsten,
Gaillard Sylvain,
Costa Rubén D.
Publication year - 2018
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.201707423
Subject(s) - fabrication , electrochemistry , copper , photoluminescence , electroluminescence , electrochemical cell , materials science , dielectric spectroscopy , optoelectronics , cationic polymerization , chemical engineering , nanotechnology , chemistry , electrode , polymer chemistry , medicine , alternative medicine , pathology , layer (electronics) , engineering , metallurgy
Recently, the use of a new family of electroluminescent copper(I) complexes—i.e., the archetypal [Cu(IPr)(3‐Medpa)][PF 6 ] complex; IPr: 1,3‐bis‐(2,6‐di‐iso‐propylphenyl)imidazole‐2‐ylidene; 3‐Medpa: 2,2′‐bis‐(3‐methylpyridyl)amine—has led to blue light‐emitting electrochemical cells (LECs) featuring luminances of 20 cd m −2 , stabilities of 4 mJ, and efficiencies of 0.17 cd A −1 . Herein, this study rationalizes how to enhance these figures‐of‐merit optimizing both device fabrication and design. On one hand, a comprehensive spectroscopic and electrochemical study reveals the degradation of this novel emitter in common solvents used for LEC fabrication, as well as the impact on the photoluminescence features of thin‐films. On the other hand, spectro‐electrochemical and electrochemical impedance spectroscopy assays suggest that the device performance is strongly limited by the irreversible formation of oxidized species that mainly act as carrier trappers and luminance quenchers. Based on all of the aforementioned, device optimization was realized using ionic additives and a hole transporter either as a host–guest or as a multilayered architecture approach to decouple hole/electron injection. The latter significantly enhances the LEC performance, reaching luminances of 160 cd m −2 , stabilities of 32.7 mJ, and efficiencies of 1.2 cd A −1 . Overall, this work highlights the need of optimizing both device fabrication and design toward highly efficient and stable LECs based on cationic copper(I) complexes.